• High-temperature (200°C), Pressurized Fuel-Cell Boasts >2 Kilowatt per

    From Larry Dighera@21:1/5 to All on Tue Oct 8 13:19:20 2024
    When the H2 fuel is pressurized, the fuel cell system gets over 2 kilowatt
    per kilogram.


    Hydrogen fuel cells are a fantastic way to generate electricity from energy dense hydrogen, that can be produces using renewable energy. This means they are a great option for low carbon transportation, especially as the
    distances get longer! However, aviation has always been a challenge. Thankfully, ZeroAvia have been working on an amazing new technology: turbo charged air cooled high-temperature pem fuel cells. These have much higher power densities and therefore enable long distance hydrogen electric flight.
    I went to their labs to check it out!

    Check out ZeroAvia here:
    https://zeroavia.com/
    With up to 60 times greater specific energy and lower cycling costs than lithium-ion batteries and numerous advantages over all other decarbonisation solutions, hydrogen-electric powertrains are the only viable, scalable
    solution for zero-emission aviation.

    Data Sheets: https://zeroavia.com/in-house-tech/

    -----------------------------------------------------------------------
    Video: https://youtu.be/BPafpvm1g3w

    0:00
    [Music]
    0:00
    this video explores a new hydrogen
    0:02
    technology that will deliver over four
    0:05
    times the power density of the fuel
    0:07
    cells currently in cars and I've been
    0:10
    granted special access to go and see
    0:12
    them in person hi I'm Val toov founder
    0:15
    in CEO Zer AIA we're here in our
    0:18
    location in Sandwich K where we have
    0:20
    high temperature fuel cell technology
    0:22
    development zero emission Aviation is
    0:25
    often seen as the final frontier of
    0:27
    clean transportation and now zero avas
    0:30
    new hydrogen fuel cells could unlock
    0:32
    flights some people thought would be
    0:34
    impossible at zero AIA we're working on
    0:37
    the next generation of power plants or
    0:39
    engine replacements for commercial
    0:

    Aviation so we're targeting larger
    0:42
    aircraft going longer distances for that
    0:45
    type of aircraft um which is the
    0:47
    majority vast majority of the emissions
    0:50
    from Aviation what's important is high
    0:52
    energy density and high specific
    0:55
    energy amount of energy that you can put
    0:57
    on the aircraft and the amount of power
    0:59
    that you can generate per unit of mass
    1:01
    and volume and that's where we believe
    1:04
    hydrogen is the only answer and hydrogen
    1:07
    electric specifically or hydrogen fuel
    1:09
    cell based power plants are the right
    1:11
    answer Time Magazine has named Zero Avia
    1:14
    the number one green tech company of
    1:17
    2024 part of this title comes from their
    1:19
    breakthrough development of
    1:21
    turbocharging high temperature hydrogen
    1:23
    fuel cells so how do high temperature
    1:26
    fuel cells work and why are they so much
    1:28
    more power dense
    1:30
    in January 2023 zero Avia flew the
    1:33
    world's biggest hydrogen electric
    1:36
    aircraft using a more standard low
    1:38
    temperature fuel cell in its powertrain
    1:41
    Regional airlines are placing orders for
    1:43
    their hydrogen Electric engines but for
    1:45
    zero Avia these are just steps towards
    1:48
    powering bigger planes that emit only
    1:50
    water vapor and heat to understand zero
    1:54
    avia's high temperature fuel cell is
    1:55
    probably useful to look at the
    1:57
    technology they're building on and
    1:59
    disrupting the most popular fuel cells
    PEM Fuel Cell
    2:02
    use a proton exchange membrane or pem to
    2:06
    induce the chemical reaction that
    2:08
    generates electricity pem fuel cells
    2:10
    were developed by General Electric
    2:12
    researchers in the 1960s and used for
    2:15
    NASA's Gemini space program there are
    2:18
    three critical components to the fuel
    2:20
    cell and they're stacked up in layers
    2:22
    the bipolar plates on either side hold
    2:24
    the whole stack together and Marshal the
    2:27
    flow of molecules the gas diffusion
    2:29
    layers usually carbon cloth or carbon
    2:31
    paper act like crowd control making sure
    2:35
    everything flows evenly into the main
    2:37
    Arena together with the catalysts and
    2:39
    membrane these make up the membrane
    2:42
    electrode assembly or mea hydrogen gas
    2:46
    and oxygen from the air arrive at
    2:48
    separate entrances hydrogen is split
    2:51
    into protons and electrons via a
    2:53
    catalyst layer usually Platinum the
    2:56
    proton exchange membrane allows the
    2:58
    protons through to the cathode but the
    3:00
    electrons can't gain entry instead
    3:04
    they're pushed through an electrical
    3:06
    circuit creating electricity before
    3:08
    reaching the cathode where they rejoin
    3:10
    the protons and oxygen to form water the
    3:14
    only other byproduct is heat so the
    Heat
    3:17
    three critical components of the whole
    3:18
    operation are the bipolar plates gas
    3:21
    diffusion layers and membrane electrode
    3:23
    assembly or mea as I mentioned before
    3:26
    most fuel cells run at low temperatures
    3:29
    they're known as LT pens and power cars
    3:32
    like the Toyota marai and new Honda CRV
    3:36
    low operating temperatures between 65
    3:38
    and 90░ C make these systems reliable
    3:41
    and durable but keeping them at the
    3:44
    right temperature requires significant
    3:46
    effort from heavy water cooling systems
    3:49
    known as part of the balance of plant
    3:51
    components not great for planes this is
    Cooling
    3:55
    where zero Avia saw an opportunity so hi
    3:58
    I'm Rudolph head of R&V zero Ava the
    4:00
    high temperature fuel cells operate at a
    4:02
    higher temperature but also for our
    4:04
    specific implementation and our novel
    4:07
    implementation of it we use direct air
    4:09
    cooling which then of course saves a lot
    4:12
    of the balance of plant components in
    4:14
    terms of we don't need additional heat
    4:17
    exchangers and we don't need additional
    4:19
    coolant pumps and you save all the the
    4:21
    coolant fluid that you that you would
    4:22
    have in the typical low temperature leid
    4:25
    cooled P fuel cell stack system this
    4:29
    seemingly simp simple change from low
    4:30
    temperature to high temperature is what
    4:32
    allows the air cooling system to work
    4:35
    because although air cooling isn't as
    4:37
    effective as liquid cooling the hotter
    4:39
    the fuel cell is the easier it is to
    4:42
    cool this is because hot things want to
    4:44
    cool down quicker than cold things as
    4:47
    well as reducing the need for complex
    4:49
    water cooling systems one of the genius
    4:51
    ways zero Avia system uses the extra
    4:54
    heat and pressure is for turbocharging
    4:57
    similar to in a car Power TR consist of
    Turbocharging
    5:00
    two main parts it's a power generation
    5:02
    part and the fuel tank with the fuel so
    5:06
    you should care about weight of both and
    5:08
    volume of both and uh efficiency
    5:11
    efficiency allow you to minimize
    5:13
    hydrogen consumption and reduce your
    5:15
    tank weight and tank volume to address
    5:17
    this challenge we developed uh two bar
    5:19
    po fuel cell system which uh combines
    5:22
    first in the world combines
    5:24
    turbocharging of fuel cells and air
    5:26
    Cooling and this allow us to maximize
    5:28
    power output
    5:30
    uh of the fuel cell system and uh to get
    5:34
    or to get over 2 kilowatt per kilogram
    5:36
    for the system level and minimize weight
    5:39
    therefore minimize weight of the system
    5:41
    when you operate at high altitude you
    5:43
    have to compress air four five times uh
    5:46
    some for high altitudes even more and
    5:48
    that's a huge power you need you have to
    5:51
    spend for compression and uh this uh
    5:54
    affects on your efficiency if you do not
    5:56
    care how how to recover uh this power
    6:00
    all G gases including reactant gases
    6:02
    passing through the system increases
    6:04
    temperature expands and uh uh can
    6:07
    provide more mechanical Power on an
    6:10
    expander on an expander and uh that's
    6:12
    the way we uh recover power uh and to
    6:16
    return this power to the system that's
    6:19
    uh one of the key Point whereas a lot of
    6:21
    low temperature systems like on the
    6:23
    Toyota marai use an electric compressor
    6:25
    to increase the pressure and therefore
    6:27
    oxygen density of the Inc air a turbo is
    6:31
    much more efficient this is because it
    6:33
    uses energy that would otherwise be lost
    6:36
    in the exhaust to spin a turbine which
    6:39
    then in turn spins a compressor that it
    6:42
    is mechanically linked to the output of
    6:44
    this compressor is oxygen dense air that
    6:47
    can then be FedEd into the fuse cell we
    6:49
    have a lot of uh extra heat and uh there
    6:52
    are a lot of uh ideas and options how to
    6:55
    use this heat for example anti-icing uh
    6:57
    procedures with htpm you had of a lot of
    7:00
    benefits and opportunities how how to
    7:03
    use this heat for for aircrafts we at
    7:05
    the beginning of our way and I believe
    7:08
    we will find a lot of brilliant ideas
    7:10
    how to use this heat and uh but the main
    7:13
    idea right now is to get light with and
    7:16
    extremely efficient power Trin power
    7:18
    system for for aircrafts and we are
    7:21
    going to have it in in the coming years
    7:23
    after hearing this I couldn't help but
    7:25
    think why isn't everyone else doing this
    7:27
    but as it turns out when you go to high
    7:29
    temperature
    7:30
    things get a lot more complicated so the
    7:32
    team took me on a tour to show me these
    7:34
    challenges and their innovative
    7:36
    solutions now the complex projects these
    7:39
    scientists and engineers at Zer AV are
    7:41
    working on may seem daunting but with
    7:44
    the right tools anyone can start
    7:46
    learning stem subjects which is why
    7:48
    before this tour I have to tell you
    7:49
    about brilliant who is supporting this
    7:51
    video and made it all possible brilliant
    7:53
    lets you learn by doing and is the best
    7:56
    way to help reach your goals for
    7:57
    understanding maths science and
    7:59
    engineering at your own pace they have
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    thousands of lessons from the basics up
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    to Advanced levels and they helped me
    8:06
    during my studies to start understanding
    8:08
    so many new topics the lessons are
    8:11
    seriously fun to do and can be done in
    8:13
    bite-sized sections to fit around your
    8:15
    busy schedule whether you're a
    8:16
    professional student or just lifelong
    8:19
    learner I've always struggled with
    8:20
    chemistry which can make fuel cells
    8:22
    pretty difficult to understand at first
    8:25
    however Brilliance courses make any
    8:27
    topic from chemistry to physics
    8:30
    approachable for anyone there are also
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    courses with fantastic real world
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    examples like getting handson with a
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    large language model similar to the one
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    progression or your own curiosity you're
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    use my Link at brilliant.org zeroth to
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    get started free for 30 days okay now
    Inside Layers
    8:52
    let's look at the inside layers of this
    8:53
    fuel cell and how they made this
    8:55
    breakthrough possible first let's see
    8:58
    how they've made incredibly lightweight
    9:00
    aluminium robust enough for the
    9:02
    corrosive environment of the fuel
    9:05
    cell i ball blade and which is very good
    9:11
    in thermal conductivity which is really
    9:13
    good in rejection of the heat produced
    9:15
    by the operation of the fuel cell uh
    9:18
    what is the challenge here that uh
    9:20
    technology operates with a phosphoric
    9:23
    acid as electrolyte and at the elevated
    9:26
    temperature up to 200░ C and in this
    9:30
    condition aluminum cannot SVP as a metal
    9:32
    so it will dissolve and uh so that was a
    9:36
    first technology we as r& the functions
    9:38
    supported to develop the special
    9:40
    protective and same time conductive
    9:42
    pting but this is just the aliminum
    9:45
    bipol plate as we get it from our vender
    9:48
    from our supplier and uh this is uh
    9:51
    really really light what we do what we
    9:53
    do here actually in this particular room
    9:56
    uh that we why the our first l or the
    9:59
    metallic lay this is a multi comp
    10:02
    multi-element uh coating several metal
    10:04
    elements and inorganic elements uh and
    10:08
    uh the function of this coating to
    10:10
    provide the
    10:11
    conductivity and to uh reduce the
    10:14
    surface resistivity of this uh plate but
    10:18
    same time to protect and to to introduce
    10:21
    some Corrosion Protection this is the
    10:23
    bare aluminum this is already with the
    10:25
    first coing layer and why is it got this
    10:28
    dimple okay this is the flow field so
    10:31
    that's that's where the reacting gases
    10:35
    uh kind of diffuse and getting
    10:37
    distributed over the surface of the
    10:39
    bipolar plate because flow field kind of
    10:42
    enables the very good diffusion and
    10:45
    penetration of the gases through the
    10:47
    whole surface of the active area because
    10:49
    that's the area where the reaction
    10:51
    happens uh this surface this particular
    10:54
    surface needs to be very very conductive
    10:56
    so that pick up these electrons and to
    10:58
    convey discharge to the to the uh kind
    11:02
    of uh current current connector here of
    11:05
    the bipolar BL see you take the aluminum
    11:08
    bipolar play and that goes into one of
    11:10
    these tanks and yeah it actually goes to
    11:13
    the different tanks and on each tank
    11:15
    there is some proces where happens with
    11:17
    the surface of this uh uh b b blade uh
    11:21
    and finally yeah the final tank is just
    11:23
    wash out all the chemicals on the
    11:25
    surface and then it's drying on the oven
    11:28
    in the oven with that I would like just
    11:30
    to mention that actually this not just
    11:33
    uh the the final look of the of the
    11:35
    bipolar plate uh to make it ready to go
    11:38
    to the stack we uh p with with a second
    11:41
    layer and this is a uh polymer composite
    11:44
    layer and actually this second layer
    11:47
    also about 5 10 microns but uh it
    11:50
    generated the major contribution to the
    11:53
    corrosion protction of the the B of
    11:55
    Blade the key purpose of all of these
    11:57
    Coatings is it primarily corrosion prot
    12:00
    and combativity yeah uh actually if you
    12:04
    if you take just the aluminum and you go
    12:07
    to the f c yeah it will survive there
    12:09
    for I don't know uh several minutes 10
    12:13
    minutes Etc but it will work uh not so
    12:19
    efficient as for example this PL with a
    12:22
    cting so those are the bipolar plates
    Bookends
    12:25
    the incredible bookends that sandwich
    12:27
    the other layers together Marshall the
    12:28
    molecu fuels and conduct electricity
    12:31
    with zero avia's proprietary coating
    12:34
    they have for the first time enabled
    12:36
    aluminium to survive the harsh
    12:38
    conditions in a high temperature fuel
    Membrane electrode assembly
    12:40
    cell next up I met chief engineer Ronda
    12:43
    Stout she showed me the main Arena of
    12:45
    the fuel cell concert the membrane
    12:48
    electrode assembly we have the ability
    12:51
    to make our own um high temperature meas
    12:54
    and what the mea consists of is cathode
    12:58
    electrode
    12:59
    and an anode electrode and then we put a
    13:02
    piece of membrane in between and it's
    13:05
    really just making a
    13:07
    sandwich and then we put this into our
    13:09
    hat press it's a toasty machine
    13:12
    basically a hat yeah like a a hat
    13:15
    sandwich what would come out would be
    13:18
    you know an assembled mea that looks
    13:21
    like this what does me stand for a
    13:23
    membrane electrode assembly and then to
    13:26
    operate it we put it between the flow
    13:28
    Fields so on one side we have our
    13:30
    hydrogen flowing and on the other side
    13:33
    is the air and that's how we um create
    13:37
    the electricity is this a testing device
    13:39
    to make sure what that previous process
    13:41
    we've done here is working right and we
    13:44
    are developing um new catalysts so that
    13:48
    we can improve the performance um and
    13:52
    make the mea better for Aviation
    13:56
    Aviation applications so then in this
    13:59
    little baby goes over into the test area
    14:03
    so we can evaluate on how well it
    14:06
    performs the electrodes Ronda showed me
    Catalyst
    14:09
    are made of a carbon cloth and have a
    14:11
    catalyst that is turned into an ink and
    14:13
    printed onto it the catalyst is an
    14:16
    essential part that splits the hydrogen
    14:18
    into protons and electrons since their
    14:21
    invention in the 1830s Platinum has been
    14:23
    used as a catalyst in fuel cells but
    14:26
    entire rods were used which turn out to
    Catalyst Coating
    14:29
    be a pretty inefficient way of using a
    14:31
    precious metal Catalyst team lead Dr
    14:34
    Aron chander Asen showed me a bit more
    14:37
    about the Catalyst
    14:39
    coating
    14:41
    uh so I'm not sure you can
    14:45
    see uh it's a platinum carbon Catalyst
    14:49
    yeah so uh you can't see Platinum the
    14:52
    reason we couldn't see Platinum here is
    14:54
    because it's mixed in with carbon known
    14:56
    as the supporting material to make the
    14:59
    the Catalyst more efficient and
    15:01
    economical is this your is this your my
    15:06
    exper why this uh measurement is this uh
    15:11
    particular measurement will give precise
    15:15
    Catalyst information so it's quicker
    15:18
    more accurate and then once you find
    15:19
    something that looks promising you can
    15:21
    make sure it works with everyone else's
    Electro Development
    15:22
    yes and finally the electro development
    15:25
    for the mea led by Dr Emerald Taylor she
    15:28
    talked to me through how they sped up
    15:30
    the reactions on the oxygen side of the
    15:31
    fuel cell to increase efficiency that
    15:34
    reaction is much slower can be a bit
    15:36
    clunky it's a bit like when you wake up
    15:38
    on a Sunday morning and you just don't
    15:39
    want to get out of bed right and we have
    15:43
    to work smartly to really get it going
    15:47
    running and working as hard as the
    15:48
    hydrogen oxidation reaction right we
    15:50
    also have to deal with the generation of
    15:52
    water there water is our V product so we
    15:54
    have gas coming in we have water VAP
    15:56
    coming out and we need to manage all of
    15:58
    that so we need to be able to reject
    16:00
    that and repel that from the cathode so
    16:02
    we can run at high current densities
    16:04
    produce more power but also man all of
    16:07
    these different nuances of the cath it's
    16:09
    a very complicated little potion that
    16:11
    we're trying to make with the bipolar
    Stacking
    16:13
    plates gas diffusion layers and membrane
    16:15
    electrc interfaces all in order it was
    16:18
    time to stack it up was to start with
    16:20
    the first pipo plate at the very end for
    16:23
    the for for the one let's say the
    16:25
    negative uh terminal and then you start
    16:27
    with the membrane Electro Sly and then
    16:29
    bu for the plate and they alternate them
    16:31
    and they stack up uh in series because
    16:34
    you B the fuel cell Stacks power also by
    16:36
    stacking all the cells in series so
    16:38
    you're trying to get a particular
    16:40
    voltage as well correct yes because the
    16:42
    uh the typical voltage for uh for a fuel
    16:45
    cell one Fuel Cell by itself at no load
    16:48
    is around about 1.2 volts or around
    16:51
    about 1.1 volt and as you draw more load
    16:53
    from it of course the voltage goes down
    16:55
    to around about 6.5 Vols this stacking
    16:58
    of cell is similar to putting batteries
    17:00
    in series to get a desired voltage from
    17:03
    the overall battery pack on the next
    Assembly
    17:05
    part of my tour Dr Sergey panoff gave me
    17:07
    some extra details about the fuel cell
    17:09
    as it starts to take its final form
    17:11
    during the assembly of the stack the
    17:13
    quality is examined and the layers are
    17:15
    built into their stack carefully using
    17:18
    guided supports this naked stack is then
    17:21
    put into a casing for testing here you
    17:24
    can see the quarter stack in one four of
    17:27
    the stack and short stti
    17:29
    uh just to validate that that everything
    17:32
    goes well and everything work properly
    17:34
    we assemble first the short stick it's
    17:37
    consist of six cells is consist of 44
    17:40
    cells and we put this equipment on a
    17:43
    test station just to validate that our
    17:46
    design Works after all of this is
    Testing
    17:48
    completed they go on to be tested and
    17:50
    validated to make sure everything works
    17:53
    as hoped as they vary parameters like
    17:55
    temperature and pressure and we want to
    17:58
    do it in as much of an isolated
    18:01
    condition so we're just evaluating how
    18:04
    the MBA the membran El form we also have
    18:09
    right
    18:10
    here oh wow a a single full size cell
    18:16
    being tested under the same conditions
    18:19
    where we can control the temperature
    18:21
    very well control the pressure very well
    18:23
    and evaluate the full size MAA the
    Applications
    18:27
    complete stack is then into a test rig
    18:30
    that looks ready for a trip to Mars the
    18:32
    rig is designed for full Stacks but on
    18:34
    the day a small stack was being tested
    18:36
    for its specific power and it was also
    18:39
    being tested for durability zavia is
    18:41
    aiming to get 10,000 hours in a future
    18:44
    iteration of the system and although
    18:46
    airplanes are the obvious application
    18:48
    high temperature fuel cells could
    18:50
    definitely be used in other places when
    18:53
    you think about other applications where
    18:55
    large powers are required like for
    18:57
    example um trucks uh heavy duty
    19:00
    Machinery Marine uh ships and even in
    19:03
    trains those are applications where HTP
    19:06
    technology can definitely bring a very
    19:09
    big Advantage U because of the thermal
    19:11
    management advantages that you have and
    19:14
    then if you put on top of that the
    19:16
    especially for mobile applications the
    19:18
    lightweight type of fuel cell Stacks
    19:20
    that we are developing and overall
    19:22
    systems that we are creating will be
    19:24
    quite beneficial for a lot of
    19:25
    applications outside of Aviation of
    19:27
    course our Focus at the moment is um
    19:30
    Aviation and this is zero Aria's Mission
    19:33
    but those um could be other
    19:35
    opportunities that could become
    19:36
    available down Steam for us as well one
    Challenges
    19:38
    big question beyond all of this
    19:40
    technology is how the production storage
    19:42
    and refueling of hydrogen would work in
    19:45
    practice zero Avia isn't just thinking
    19:47
    about the technology in their fuel cell
    19:49
    but on the entire chain from hydrogen
    19:52
    production through to its use to bzero
    19:54
    emissions they'd have to use green
    19:56
    hydrogen so they are making their own
    19:59
    and partnering with other providers
    20:01
    though this will become a much larger
    20:03
    project as more planes take to the Skies
    20:05
    of course uh there are challenges on
    20:07
    this uh path and if there were no
    20:09
    challenges they would have been done
    20:10
    already um and it hasn't been so there
    20:13
    are challenges but uh we believe that we
    20:15
    can solve them uh some of them include
    20:18
    regulatory environment for example right
    20:20
    it's new technology Aviation is a
    20:22
    regulatory heavy industry things take
    20:25
    time um but uh we've been working with a
    20:28
    regulat
    20:29
    in the US in the UK and in Continental
    20:32
    Europe for a number of years now uh we
    20:34
    have flown a number of prototypes so The
    20:36
    Regulators are very familiar with our
    20:38
    technology so we believe we can actually
    20:40
    push the first uh set of uh engines into
    20:44
    the Market within the next two years two
    20:46
    two and a half years so 2025 2026 some
    20:49
    regulations are also working in zero
    20:51
    avia's favor as they make traditionally
    20:53
    fueled flight more expensive and as
    20:56
    subsidies are given to cleaner
    20:57
    Alternatives using us renewable energy
    20:59
    gives operators significant cost
    21:01
    advantages changing commercial Aviation
    21:04
    over to hydrogen is a huge challenge but
    21:06
    with a step change in fuel cell
    21:08
    technology from turbocharged high
    21:10
    temperature fuel cells combined with
    21:12
    global efforts and funding there's
    21:14
    something seriously going on here of
    21:17
    course there are some who think this is
    21:19
    too big of a challenge then again the
    21:21
    same was said for solo flight across the
    21:23
    Atlantic and space travel if you've
    21:26
    enjoyed this video please subscribe it's
    21:27
    free and help support this channel a lot
    21:30
    to make videos like this possible I also
    21:32
    think you might like some of my other
    21:33
    videos like this one on a new type of
    21:35
    propeller and as always thanks for
    21:41
    watching



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